Automation is a huge part in how "easy" a tank is to take care of. If you compare tasks on a huge tank vs. a small tank, you wont see a huge swing in time for most of them.
Testing parameters will be the same on both tanks, regardless of volume of the tank, you are still testing 2-10mL of water depending on the test. Hanna Checkers are a good way to speed up the time it takes to test water.
Dosing will be similar on both tanks. You might dose 4x on a 100 gallon vs. a 25 gallon, but the amount of time you will save on pouring in additives is seconds at best. Instead, look into getting dosing pumps that do this for you.
Feeding will be similar on both tanks. You will definitely have more fish in the larger tank, but you could also put more food in at once. I don't think there is anything you can do to speed this up other than look into a controller that turns everything off and on for you. That would be a good way to save a minute or two/day.
Water changes will be the biggest difference you see. Changing 25 gallons of water takes WAY longer than changing 5 gallons of water. If this is the issue, maybe look into automating the process a little bit. For me, the biggest change that I've made was using a brute to move 25 gallons at a time instead of doing the 5 gallon bucket nightmare.
Cleaning the tank will be faster on the smaller tank for sure, but the smaller tank may also get dirtier, quicker due to water parameters.