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Ok so before I get into my problem ill describe my setup. I have a 215 gallon sps tank thats been setup around a year. I have all top of the line equipment bubble king skimmer, vortechs, chiller, phosphate reactor, uv sterilizer and the works. I have around 15 fish, 6 tangs, 4 anthias, and some other dwarf angels and such. A few days ago i noticed my tangs had come down w ick-a problem i havent had in around 4 months- and much worse than before. I immediately tested everything and all seemed well except nitrates. and they were off the charts with the salifert kit. This is ironic bc i just bought a denitrator to cope with my problems of 30-40 nitrates last week. I setup the denitrator around 5 days ago and moved 20-30 lbs of rubble rock from the end of the sump to right under the overflow into the sump to fit the denitrator. 3-4 days later i noticed my nitrates were the highest level on the chart. I've done two 50% changes in the past 3 days and they are still registering at 100 on my salifert kit. now originally i thought moving my rubble rock to under the overflow caused it to release alot of bound organics causing a large nitrate spike. but now after performing two 50% changes with no change in nitrates i'm beginning to suspect my DSB is crashing. today i lost a yellow tang, and dori looks terrible. Suprisingly my powder blue looks the best of any of the tangs. Essentially my questions are would rock be able to release this much nitrate (Wed 30-40) Sunday (100+)? If sandbeds crash do they release nitrates? and finally If my sandbed is crashing what option do i have to save my animals? Another note, My corals look better than ever, this is absolutely odd but they do and the sand has no H2S smell so i dont believe its sulfide.