I would try a different alk test. Are you using a titration test or other test?
Here is why I ask, at a dKH of 20+, you would most likely have the alk drop out of solution and you would KNOW that there is a major problem.
What salt are you using, Instant Ocean has had reports of making the dKH raise to about 18 but I have never heard above that.
Have you tested your dKH of your source water? Might be worth a check. Have you tested the dKH of your new salt water before you add it to the tank? Might be worth a check.
Are you running a calcium reactor?!?
You can use a weak acid, like vinegar to bring the dKH down but I would only use a SMALL amount at a time and test after about 12-24 hours.
What is your calcium and mag?!?