This is one of the best discussions I've read, about the relationship of calcium and alkalinity, by Randy Holmes Farley a chemist and reef aquarist.
It has a graphical representation as well, which helps us to visualize where the parameters are and where we need them to be. Then discusses how to get there.
A little long, but also a great read imo -
I hope this article proves useful is understanding and dealing with the different types of calcium and alkalinity problems encountered by reef keepers. Once you get calcium and alkalinity under control, you are far along the road to having your tank chemistry optimal for its inhabitants.
reefs.com