grouper therapy;717438 wrote: What is wrong with the larger water changes?
+1 ^
You actually leave more nutrient (larger %) after a smaller water change. It's due to the dilution factor. Many smaller fractions vs one larger fraction. Four 10% water changes does not equal 40%. It equals 34.39%.
Here's the math-
100 x 0.9= 90
90 x 0.9= 81
81 x 0.9=72.9
72.9 x 0.9= 65.61%, so
100 - 65.61= 34.39%, an almost 6% difference from one 40% water change.
As for nitrate/phosphorous-
if this has been high for any length of time, and you have any significant substrate/sand/gravel (it goes into the live rock too), then you will have stored a good bit of the nitrate and phosphorous in that substrate. Simply doing water changes will temporarily change the nitrate/phosphorous concentration in the tank water, until the concentration difference between what's in the substrate and tank water equilibrates (equalizes). The nutrients in the substrate will come out/leach into water with a lower concentration of nutrients, but it does so slowly.
Or, in other words the nitrate/phosphorous stored in your gravel/rock will continuously leach back into your tank water after water changes. This is why many hobbyists get so frustrated and don't feel water changes help lower the nutrients. It will, but it will take time. This is sometimes referred to as 'old tank syndrome'. This is most of the reason why you are seeing the nitrate back up after a week, although some additional nitrate/phosphorous is being added continuously as well.
http://www.advancedaquarist.com/2006/5/aafeature2">http://www.advancedaquarist.com/2006/5/aafeature2</a>
When people with older tanks start carbon dosing for instance, they see the effects of this too. They don't see the same results as people with newer systems and come to the (incorrect) conclusion that 'it doesn't work for them'. It will, but will take more time to get all of those stored nutrients back out of the substrates.
So, what to do?
1) be patient and consistent with water changes over a longer period of time (dilute the nutrients). Or,
2) change out your substrate. This can be done a bit at a time, but I prefer to just do it all at once. A system re-boot if you will. Or,
3) adopt a more advanced method for nutrient export, which can include- growing macroalgae, algal turf scrubbers, denitrifying reactors, carbon dosing, etc.
Whatever you choose to do, I suggest that you learn exactly how it works and why. Only then will you be sure of success and recognize when/why things happen.
Hope this helps.