Not looking to 'prove' anyone either right nor wrong, but offer the following links for reference. The first is an article by Randy Holmes-Farley a chemist/hobbyist. The second is a great reference point article for things diatom related. The second one, I think, offers a good perspective on this issue, and some good academic links as well. Hope this helps...
http://www.advancedaquarist.com/issues/jan2003/feature.htm">http://www.advancedaquarist.com/issues/jan2003/feature.htm</a>
and
[IMG]http://www.skepticalaquarist.com/docs/algae/diatoms.shtml">http://www.skepticalaquarist.com/docs/algae/diatoms.shtml</a>