I use Purigen on every one of my tanks. I've got a few different bags that I'm always recharging and putting back into service. It's hard to tell exactly how well they work compared to carbon because I don't necessarily measure the organics that they remove. I use them because when I put them in nice and clean, after a few weeks they're gross and dark brown. They've got to be doing something, right? The purigen is on all the time and I only run carbon when I think something might be wrong, after I've scrubbed polyps or palys or when I want to increase the water's clarity. For chemical or toxin removal I trust carbon. As a regular-use export of organic compounds, Purigen is my weapon of choice.
I have it in my head that Purigen is a little, I don't know, "gentler" on things? Unfortunately for you and anyone reading this I don't have hard evidence to back this up, it's just my own perception.