What's the best Ozonizer or Ozone Generator?

Correct me if I am wrong please Dave but when you said " You won't see a spike in system ORP in a setup like this because the ozone is applied and removed separate from the DT." you were not suggesting that by simply using a reactor ,the orp levels would not SPIKE . Rather that the system you have running ,the reactor and the total volume of water passing over GAC would not drastically raise your ORP levels? So barring any failure of the system or the operator this system it would be impossible for it to spike the ORP since it the ozone is being removed.
 
Well looky looky here! :yay: Cleaning out the basement storage I came across a box of stuff I kept from my reef 20 years ago. Thought I had lost it and had looked for it several times. Anyway, I was the only person I knew back then running ozone through my skimmer. It was on a nano 10g reef at the time. (I was told at the time, to keep a 10g reef was impossible due to the small margin of error. So, that meant I had to do it)

It's a Le Mer Megazone 400 ozonizer. This is a beast! 720mg an hour! :eek: Don't even try Googling it because you'll come up empty. I got it straight from the manufacturer through a friend of a friend. Was told it could run an entire LFS system. I would only run it once a week for about ten minutes. The thing couldn't have more than 10 total hours on it. Gotta think it's just fine.
I feel like I'm dropping a big block 454 into a Honda Accord here. I don't think running this 24/7 is an option. I either need to figure out how to use it best or trade to someone with a monster system.
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grouper therapy;645218 wrote: Correct me if I am wrong please Dave but when you said " You won't see a spike in system ORP in a setup like this because the ozone is applied and removed separate from the DT." you were not suggesting that by simply using a reactor ,the orp levels would not SPIKE . Rather that the system you have running ,the reactor and the total volume of water passing over GAC would not drastically raise your ORP levels? So barring any failure of the system or the operator this system it would be impossible for it to spike the ORP since it the ozone is being removed.

Right Dave. Thank you for pointing that out. The ozone itself in an ozone reactor with post reactor GAC filtration wouldn't spike the ORP from actual ozone getting into the system water because the ozone is removed from the water.

Any rise in system ORP (total reef water volume) you would see from the use of a reactor system with GAC would be from the reactor decreasing the total amount of reducers (- charged organics) in the system. Decrease the total amount of negatively charged reducers, and you increase the net positive charge of the system (ORP), as measured by the ORP probe/monitor.

Same principle with water changes or other nutrient (reducer) exporting practices. Pull a volume of water out of the system, you are taking a certain amount of organics (- charged reducers) out of the water, thereby reducing the negative charge of the system, and increasing the net positive charge (ORP) of the system.
 
Acroholic;645206 wrote: ORP is a voltage measurement of the overall potential of oxidizers (+ charged ions like ozone) in our tank water to accept electrons from reducing agents (- charged ions), including those organics we want to remove from our systems. For example, organics that color our tank water.

Ozone is a powerful oxidizer, and while ozone is a substance and ORP is a voltage measurement, and may be separate, excess ozone in tank water will raise ORP by increasing the positive voltage measured by the ORP probe.

A higher ORP is beneficial to a point, but over a certain level you will oxidize coral and fish flesh as well as excess organics.

Yes, you can raise the ORP of your tank water by different means, like removing contaminants (reducing agents) through water changes, mechanical filtration, skimming, UV, but I have never experienced or read of ORP being raised to dangerous levels thru regular tank maintenance.

That is why it is important to monitor ORP when you use ozone, because it can raise ORP to a much higher degree than something like a water change. There is a big difference in using ozone vs regular maintenance practices because of how quickly ozone can be overdosed in a reef system.

The above JMO.

Yes, Dave, that is all factually correct, about oxidiation. Ozone is a powerful oxidizing agent, by being able to accept electrons. The reason ozone is dangerous is because it doesnt ONLY oxidize organics. It will oxodize near everything that can be oxodized. Including gill tissue and coral tissue. Hence the danger.

However, you are still misapplying the technical terminology. In particular:
A higher ORP is beneficial to a point, but over a certain level you will oxidize coral and fish flesh as well as excess organics.

ORP doesnt oxidize. Ozone is one of MANY things that will. High ORP doesnt kill because it oxidizes. Oxidation can cause high ORP. Oxidation can kill. But you cant say that High ORP kills through oxidation. That is kinda apples and oranges.

ORP is a very complicated and balanced "equation". Having a high ORP doesnt mean you have too much ozone in your water, even if you are using ozone. It merely means that you have a greater potential for reduction, rather than oxidation. That can be through a huge number of means.
 
jmaneyapanda wrote: However, you are still misapplying the technical terminology. In particular:
A higher ORP is beneficial to a point, but over a certain level you will oxidize coral and fish flesh as well as excess organics.
ORP doesnt oxidize. Ozone is one of MANY things that will. High ORP doesnt kill because it oxidizes. Oxidation can cause high ORP. Oxidation can kill. But you cant say that High ORP kills through oxidation. That is kinda apples and oranges.

I never said ORP oxidizes. You pulled this sentence out of context, out of the middle of a post in which I clearly stated "ORP is a voltage measurement of the overall potential of oxidizers (+ charged ions like ozone) in our tank water to accept electrons from reducing agents (- charged ions), including those organics we want to remove from our systems."

I also stated in the same post "Ozone is a powerful oxidizer, and while ozone is a substance and ORP is a voltage measurement, and may be separate, excess ozone in tank water will raise ORP by increasing the positive voltage measured by the ORP probe."

The above indicates a clear delineation between ORP as a voltage measurement (reduction potential) and ozone as an oxidizer. The context of this discussion, or at least what I am trying to address, is the reef hobbyist using ozone and possible overdosing of ozone, with an elevated ORP level (seems to be +400-450 mv or higher) being the best indicator of an ozone overdose, or the presence of excess ozone, or too many oxidizers (O3 use or not) in the system, however you want to look at it.

jmaneyapanda wrote: Oxidation can cause high ORP.
I can do the same thing here regarding misapplication of terminology. Oxidation does not cause high ORP. Oxidation actually lowers ORP by decreasing the overall positive ORP voltage as a reducer donates electrons to an oxidizer. The presence of oxidizers, like ozone, can cause high ORP. But I understand what you were trying to say in the context of your post.


jmaneyapanda wrote: ORP is a very complicated and balanced "equation". Having a high ORP doesnt mean you have too much ozone in your water, even if you are using ozone. It merely means that you have a greater potential for reduction, rather than oxidation. That can be through a huge number of means.
Agreed. System ORP is the result of many ongoing reactions. But since this thread is in the context of the Reefer using Ozone in his system, and relative to other means of increasing ORP, like water changes, etc., ozone overdose can be harmful to fish and corals in a relatively short period of time, monitoring ORP can indicate excess ozone in the system, in addition to all other reactions that contribute to the ORP voltage reading. If I start using ozone in my system, and my maintenance practices are unchanged, and my ORP goes from 275 pre-O3 to 500 post-O3, then that is probably a good indication I am using too much ozone and I have to do something about it.
 
so..

those things being said...

What are the target ORP numbers to look for? (200's? 400's?) (what's normal/preferred?)

...and if I'm NOT using Ozone, what could be causing them to be too high or too low?


...and what do I do to put them back into normal range?
 
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