@Eric_n_Ga No you don't want to do a loading dose per se, if you raise the Alk too quick you can start precipitation. If that happens it kinda goes runaway until you can get it to stop, by not dosing anything for several days to a week. Most places say not to raise Alk by more than 1.4dkh a day. With a new system I'd halve that, 0.7dkh/day, so you don't start preciping.
This is what I would do.
Stop dosing till at least Tuesday 7/7, longer if the Cal is still high at that time.
Make a couple of large water changes 30% to 50%. Do like one a today and one tomorrow. This will help re-balance the system. It would also be a good idea to cut the photo period on the fuge to 4-6hrs per day till Monday or Tuesday. Those water changes will lower your nutrients a good bit.
Wait till Saturday to test Alk so the system has time to stabilize. It should have rebounded some but the Cal may still be a little high but I would even test that till Sunday.
Now is the time to adjust the Alk if it needs it. First double check the Mag and make sure it's in line. Then figure out how much you need to dose to get to your target, be it 8 or 8.5dkh, without exceeding a 0.7dkh rise. Splitting the dose in two a couple hours apart. Add the dose to a very high flow area of the tank.
If you needed to make an adjustment to the Alk test the Cal the next day, it will have dropped some. But if it's still above 425 don't start dosing All for Reef until it drops to that or lower. Ionic balance of Cal with an Alk dkh of 8.5 is 421.
Now I'm guessing Cal will still be a little high. So you'll need to do Alk only dosing daily or via a doser until you it get back in line. Just be careful not to raise it too much at one time.
I think the system is still to new to require a balanced dosing program as it will continue to use more Alk than Cal for a while, which means the Alk will drop and Cal will start rising again. Start your AFR dosing back at the same level as you had on the 29 and keep an eye on those two and make Alk adjustments as need to correc
It's going to be impossible to just dose AFR until the excess Alk demand levels off. You also can't base your AFR dose amount by that Alk demand because the Cal will start rising. The bacteria sucking up the Alk doesn't use any Cal. This definitely makes the situation more difficult but you will be able to work through it, at the cost of more frequent testing for a while. All in All I'd say you did everything right starting up the 75. This is just a variable where there isn't a work around. The system just needs to mature.
Keep us updated and if you run into any problems we'll be here to help.