When I've used All-For-Reef (AFR) I had the exact same experience. CA would be maintained but I still had to dose Alk to keep it up. Based on research and conversations with people smarter than me, here's what I believe is happening:
AFR is balanced in the correct ratio of CA/Alk for corals to take it up. However, there are a lot of processes in our reef tanks that take up carbonate besides coral. If it was just coral growing, the AFR would be sufficient. Corals take CA/Alk up in a known and balanced ratio but the rest of my the tank uses carbon from Alkalinity to grow and doesn't have anything to do with Calcium. After a few weeks of dosing it, the disparity became less and less but once I got my AFR dose "dialed in" I would still test and dose Alk a few times a month to keep the levels where I wanted them.
AFR is balanced in the correct ratio of CA/Alk for corals to take it up. However, there are a lot of processes in our reef tanks that take up carbonate besides coral. If it was just coral growing, the AFR would be sufficient. Corals take CA/Alk up in a known and balanced ratio but the rest of my the tank uses carbon from Alkalinity to grow and doesn't have anything to do with Calcium. After a few weeks of dosing it, the disparity became less and less but once I got my AFR dose "dialed in" I would still test and dose Alk a few times a month to keep the levels where I wanted them.